Glyceollins are a family of prenylated pterocarpan found in ineffective types of nodule in soybean in response to symbiotic infection
It possesses two chiral centers and can be asymmetrically synthesized chemically at a gram level scale
They are phytoalexins with an antiestrogenic activity
Molecules found in the family are :
- Glyceollin I
- Glyceollin II
- Glyceollin III
- Glyceollin IV
Glycinol is the direct precursor of glyceollins through the action of a prenyltransferase Glyceollin synthase then transforms those prenylated precursors into glyceollins
- ^ Soybean root response to symbiotic infection: Glyceollin accumulation in an ineffective type of nodule with an early loss of the peribacteroid membrane Werner, D, RB Mellor, MG Hahn and H Grisebach 1985, Z Naturforsch, 40, 171-181
- ^ Luniwal, Amarjit; Khupse, Rahul; Reese, Michael; Liu, Jidong; El-Dakdouki, Mohammad; Malik, Neha; Fang, Lei; Erhardt, Paul 2011-09-16 "Multigram Synthesis of Glyceollin I" Organic Process Research & Development 15 5: 1149–1162 doi:101021/op200112g ISSN 1083-6160
- ^ Glyceollins, a Novel Class of Antiestrogenic Phytoalexins Syreeta L Tilghman, Stephen M Boué and Matthew E Burow, Mol Cell Pharmacol 2010;24, pp 155-160, doi:104255/mcpharmacol1021
|See also Receptor/signaling modulators Estrogens and antiestrogens Androgen receptor modulators Progesterone receptor modulators List of estrogens|
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