Epietiocholanolone, also known as 5β-androstan-3β-ol-17-one or as etiocholan-3β-ol-17-one, is an etiocholane 5β-androstane steroid as well as an inactive metabolite of testosterone that is formed in the liver The metabolic pathway is testosterone to 5β-dihydrotestosterone via 5β-reductase, 5β-dihydrotestosterone to 3β,5β-androstanediol via 3β-hydroxysteroid dehydrogenase, and 3β,5β-androstanediol to epietiocholanolone via 17β-hydroxysteroid dehydrogenase Epietiocholanolone can also be formed directly from 5β-androstanedione via 3β-hydroxysteroid dehydrogenase It is glucuronidated and sulfated in the liver and excreted in urine
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